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Norm
ÖNORM EN 13368-2
Issue date: 2007 06 01
Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 2: Determination of Fe chelated by o,o-EDDHA and o,o-EDDHMA by ion pair chromatography
This document specifies a method for the chromatographic determination of the iron chelated by each
individual ortho(hydroxy)-ortho(hydroxy) isomer of the chelating agen...
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Withdrawn
: 2012 10 01
Publisher:
Austrian Standards International
Format:
Digital | 18 Pages
Language:
German
| English
| Download GER/ENG
Currently valid:
Optionally co-design standards:
ICS
This document specifies a method for the chromatographic determination of the iron chelated by each
individual ortho(hydroxy)-ortho(hydroxy) isomer of the chelating agents o,o-EDDHA and o,o-EDDHMA in
fertilizers containing one or both of these substances. The method allows the identification and the
determination of the total concentration of water soluble iron chelates of these chelating agents. It does not
determine the free form of the chelating agents.
NOTE 1 The substances EDDHA (ethylene diamine di(hydroxy phenyl) acetic acid) and EDDHMA (ethylene diamine
di(hydroxy methyl phenyl)acetic acid) exist as several different isomeric forms. Positional isomers for the hydroxyl or
methyl groups (in ortho, meta, and para positions) as well as stereo isomers (meso and dl-racemic forms) are known. Both
meso and dl-racemic forms of the ortho,ortho-EDDHA and ortho,ortho-EDDHMA are positional isomers for the hydroxyl
groups allowed by the Regulation (EC) No 2003/2003. Since para, meta and ortho methyl positional isomers of the
EDDHMA present quite similar stability, they could be grouped: in the method here described the para, meta and ortho
methyl positional isomers of the o,o-EDDHMA are considered together.
NOTE 2 At present, analytically pure standards only exist for ortho,ortho-EDDHA and ortho,ortho-EDDHMA. All other
substances being unavailable as a standard, the influence of their eventual presence in the samples (with respect to the
sensitivity and the selectivity of this method) has not been studied.
NOTE 3 The meso and the dl-racemic forms of o,o-EDDHA and o,o-EDDHMA can be determined separately by this
method.
This procedure concerns EC fertilizers covered by Regulation (EC) No 2003/2003 [5]. It is applicable to a
mass fraction of the metal chelated of at least 0,625 %.
ÖNORM EN 13368-2
2018 03 15
Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 2: Determina...
Norm
ÖNORM EN 13368-2
2012 10 01
Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 2: Determina...
Norm
ÖNORM EN 13368-2
2007 06 01
Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 2: Determina...
Norm
↖
ÖNORM EN 13368-2
2001 04 01
Fertilizers - Determination of chelating agents in fertilizers by ion chromatography - Part 2: EDDHA...
Norm
Norm
ÖNORM EN ISO 3696
Issue date :
1995 08 01
Water for analytical laboratory use - Specifications and test methods (ISO 3696:1987)
Norm
ÖNORM EN 1482-2
Issue date :
2007 04 01
Fertilizers and liming materials - Sampling and sample preparation - Part 2: Sample preparation
Norm
ÖNORM EN 13368-2
Issue date :
2012 10 01
Fertilizers - Determination of chelating agents in fertilizers by chromatography - Part 2: Determination of Fe chelated by o,o-EDDHA, o,o-EDDHMA and HBED by ion pair chromatography